

with Jim, Kevin and Rob at Lake Lila in the Adirondacks |
Ann Silversmith
email: asilvers@hamilton.edu
phone: (315)859-4704 fax: (315)859-4807
Education
Ph.D. in physics from the Australian National University, January 1986.
Thesis title: "High Resolution Laser Spectroscopy of Trivalent Europium
Centers in Crystals".
M.Sc. in physics from the University of Wisconsin, May 1982.
A.B. from Oberlin College, May 1978. Majored in physics. Graduation with
high honors.
Experience
PROFESSOR (2002-, chair 2004-), ASSOCIATE PROFESSOR (1995-2002), ASSISTANT
PROFESSOR (1989-95), Department of Physics Hamilton College.
Research in the field of laser spectrocopy of solids. Current project
involves the synthesis and spectroscopic characterization of rare-earth
based sol-gel glasses.
VISITING FELLOW (Jan.1998-May 1998), Laser Physics Center Research School
of Physical Sciences, The Australian National University ,Canberra, A.C.T.,
2601, Australia.
Research involving spectroscopy of rare earth doped sol-gel glass, holeburning
and optically detected nuclear magnetic resonance of Europium doped fluoride
crystals, and laser-induced upconversion in Er:KLiYF5.
VISITING SCIENTIST (Feb. 1986-May 1987) IBM Almaden Research Center 650
Harry Road San Jose, CA 95120-6099.
Research in the field of high resolution holeburning spectroscopy, and
research and development of upconversion-pumped lasers.
GRADUATE STUDENT (Sept. 1982-Dec. 1985) Research School of Physical Sciences
The Australian National University. Canberra, A.C.T., 2601, Australia.
GRADUATE STUDENT (Sept. 1979-May 1982) Department of Physics University
of Wisconsin Madison, Wisconsin 53706.
For more information and photos, follow this
link. |
Research In Laser Spectroscopy of Rare Earth Based Solids
When I arrived at Hamilton, I concentrated most of my effort on
the spectroscopy of upconversion laser materials. I got into this
field as a post-doc at IBM. I was a member of the Optical Storage
group there that was working on the development of compact blue laser
devices. An Upconversion Laser produces laser light at a higher
frequency than the pump light - hence the name - and is one possible
way of creating a blue laser using readily available infrared diode
lasers as excitation sources. Our group at IBM built the first
continuous upconversion laser and then developed several more lasers
before I left in mid-87. Since then, the field has grown and many
groups all over the world are working on upconversion.
Many students have done summer research and senior projects in my
lab; some of our work has been published and/or presented at
international conferences. Last summer I presented two posters at DPC
(Dynamic processes Conference) in France with student co-authors
Rachael Anderman ('01)David Shaye, Bryan Smith (both '02), and
Lynwood Rumney (04). A few years ago I presented an invited paper at
the International Conference on Luminescence (ICL) in Prague (August
'96) which had two Hamilton students as co-authors: Ed Bielejec '96
and Ema Kisel '97. A number of years ago Brandon Collings, a research
student in my lab during the 93-94 academic year, won a national
award (The Apker award, given by the American Physical Society) for
his project.
While at ICL '96 I heard a talk about sol-gel synthesis of Rare Earth doped
glass and thought it sounded like fun - something that could be done at Hamilton.
Since summer '97 I've been working with Karen Brewer in the chemistry department
here and Dan Boye, in physics at Davidson College, on making glass and doing
interesting spectroscopy on our own materials. We've had a grant from Research
Corporation to support the project and have had many students make valuable
contributions to the work. In the summer of 2003 Dan and I presented two posters
of RE-based sol-gels at the Dynamic Processes Conference in Christchurch, NZ.The
paper on chelation of rare earth ions was based on research carried out by Andrew
Magyar '03.
More recently, Greg Armstrong '06 made Y2O3"Eu3+
nanoparticles and attempted to incorporate them into a sol-gel matrix. It's
been fun and we've learned a lot, but so far our particles have not survived
intac. Brendan Sullivan '07 used Tb3+ in sol-gel glasses to investigate
energy transfer among rare earth ions. He studied the variation in intensity
of 5D3 emission with annealing conditions. This summer
Yubo Lu '07 and Dan Campbell '08 are continuing the work with Tb3+.
They are studying the aging of sol-gel samples after annealing.
Courses Taught
I have taught introductory physics for science majors and pre-meds, a course
about lasers specifically designed for students from outside the sciences, several
intermediate level physics courses for physics majors, and have directed senior
research projects. Physics 100-105, our introductory course called Survey of
Physics, is a fairly standard first year physics course. The other 100-level
course that I teach is Physics 140 - "Light and the Laser", a course for nonscientists.
The classes have been made up of interesting collections of students: first-years
through seniors, with majors ranging from art to religion to economics to.....
Our syllabus covers geometric optics, E and M, wave theory of light and physical
optics, and early quantum theory then moves on to specifics about lasers. For
the past few years I've taught "Modern Physics", but we've recently renamed
it "Quantum Physics" because we concentrate on physics before 1940 - not so
Modern anymore. Last spring I led juniors through an advanced lab course to
get them prepared for their senior research projects. I've also taught Statistical
Physics and Classical Mechanics over the years.
Research Grants
Petroleum Research Fund “Fluorescence from Sol-gel Materials doped with
Rare Earth Impurity Ions”, in collaboration with D.M. Boye, Davidson College,
$50,000 for 2005-2008. Research performed at Hamilton and Davidson Colleges.
National Science Foundation MRI Program “Acquisition of Equipment for
Thermal and Optical Studies of Sol-gel Materials Containing Rare Earth Ions”
Co-PI, in collaboration with D.M. Boye, Davidson College,. $150,000 for 2004-20007.
Research performed at Hamilton and Davidson Colleges.
Research Corporation, "Synthesis and Characterization of Rare-Earth Doped Sol-Gel
Glasses". In collaboration with Karen Brewer. Funding for 2000-01.
National Science Foundation Research at Undergraduate Institutions
(RUI) Grant #DMR - 9101364, "Spectroscopy of Upconversion Laser
Materials". $80,000 for 1991-95. Research performed at Hamilton
College.
Research Corporation, "Spectroscopy of Upconversion Processes in
Rare-Earth Based Solid State Laser Materials" $33,750 for purchase of
laser equipment for spectroscopy laboratory at Hamilton College.
1991.
Research with Undergraduates
- Tessa Olson (Summer 2005) "Impact craters in granular media"
- Yubo Lu (Summer 2005) " Tb3+ as a probe of dehydroxylation
and rehydroxylation in sol-gel glasses"
- Dan Campbell (Summer 2005) " Tb3+ as a probe of dehydroxylation
and rehydroxylation in sol-gel glasses"
- Greg Armstrong (Summer 2004) "Combustion synthesis of Y2O3"Eu3+
nanocrystals"
- Brendan Sullivan (Summer 2004) "5D3 emission
in Tb3+ doped sol-gel glass"
- Andrew Magyar (Academic year 02-03) "Using Chelating Agents in Sol-Gel Synthesis
to combat the OH Radical Problem" Presented at DPC '03 in Christchurch, NZ.
- Stephanie Higgins and Daniel Allen (Summer 02) "Effects of Different Co-dopants
on Fluorescence Quenching in RE based Sol-Gel galsses" Presented at Summer
Research Poster Session, Hamilton College.
- David Shaye (Academic year 01-02) "Evidence for divalent Europium in sol-gel
silicate glasses"
- Jessie McComb (Summer 2001) "Fluorescence line-narrowing and decay dynamics
in sol-gel glasses containing Eu3+"
- Rachael Anderman (Academic year 00-01, Summer 99) "Holeburning Study of
Eu-Doped Sol-Gel Glass" and "Spectroscopy of TiO2/SiO2
Binary Glasses made by the Sol-Gel Method"
- Linwood Rumney, David Shaye and Bryan Smith (Summer 00) "Increased Upconversion
Efficiency in Er-doped sol-gel glasses containing Titanium". Presented at
Sigma Xi Summer Research Poster Session, Hamilton College.
- Brian Lancor (Academic year 99-00) "Spectroscopy of Rare Earth doped Sol-Gel
Glass".
- Allen Otto, (Academic year 98-99) "Upconversion processes in Rare Earth
doped Sol-Gel Glass"
- Jon Silber (Academic year 97-98) "NMR Study of the gelation process in sol-gel
synthesis"
- Matt Hornbach (Summer 97) "Synthesis and Spectroscopic Characterization
of Rare earth Doped Sol-Gel Glasses", in collaboration with Daniel Boye, Davidson
College, Karen Brewer, Jannett Matthews '99 and Jeff Garte '00, Hamilton College
Chemistry department.
- Debbie Hamilton (Academic year 95-96) "Upconversion in Doubly Doped (Pr
and Nd) Materials ".
- Mary Dias and Ed Bielejec (Summer 1995) "Avalanche Effect in Nd:YLF", "Characterization
of a Visible Diode Laser", Presented at the 30th Anniversary of Sigma Xi Poster
Session, Hamilton College. Stipends from RUI grant.
- Jahon Hobbeheydar (Academic Year 94-95) "Upconversion in Nd:YLF" Presented
at "National Conference on Undergraduate Research (April 1995),
- Ema Kisel and Ed Bielejec (Summer 1994) "Avalanche Upconversion In YSO:Tm3+
"Presented at the International Conference on Luminesence (ICL '96). Stipends
from the Hughes and Bristol Myers Grants.
- Brandon Collings (Academic year 93-94) "Photon Avalanche In LaF3:Tm3+
"Results presented at Conference on Lasers and Electro-Optics (CLEO), May
1994. Winner of national Apker Award for undergraduate research in physics.
- Amy Shapiro and Jahon Hobbeheydar (Summer 1993) "Laser Spectroscopy of BaF2:Eu3+",
Stipends from the Hughes Grant and National Science Foundation.
- Robin Ketcham (Academic year 91-92)"Low Temperature Upconversion Spectroscopy
in YAlO3:Er3+"Presented at the 12th Annual Rochester
Symposium for Physics Students.
Publications (* denotes student author)
- A.P. Magyar*, A.J. Silversmith, K.S. Brewer, and D.M. Boye, "Fluorescence
enhancement by Chelation of Eu3+ and Tb3+ ions in sol-gels",
J. Lumin. 108, 43 (2004).
- R.E. Anderman*, A.J. Silversmith, K.S. Brewer, T.S. Valdes*, J.H. Nolen*
and D.M. Boye, R.S. Meltzer, "Transient and Persistent Spectral Hole Burning
in Eu3+-doped sol-gel produced SiO2 glass", J. Lumin.
108, 49 (2004).
- A.J. Silversmith, D.M. Boye, R.E. Anderman* and K.S. Brewer. "Fluorescence
line-narrowing and decay dynamics in sol-gel glasses containing Eu3+",
presented at DPC, Lyon, France July 2001 and J. Lumin 94-94 275-278 (2001).
- D.M. Boye, A.J. Silversmith, J. Nolen*, L. Rumney*, D. Shaye*, B.C. Smith*,
and K.S. Brewer, "Red-to-green upconversion in Er-doped SiO2 and SiO2/TiO2
sol-gel silicate glasses", (DPC, Lyon, France July 2001) and and J. Lumin
94-94 279 (2001).
- A. Smith, N.B. Manson, A.J. Silversmith, and B. Henderson, "Site Selective
Excitation and Upconversion in Er3+:KLiYF5", Optics
Communications 188, no1-4, 219 (2001).
- Allen P. Otto*, Karen S. Brewer and Ann J. Silversmith, "Red to Blue Upconversion
in Tm-doped sol-gel silicate glasses", J. Noncryst. Solids 265, 176-180 (2000).
- E. Bielejec*, E. Kisel* and A. Silversmith, "Red to Blue Upconversion in
Y2SiO5:Tm3+", J Lumin. 72-74, 62 (1997)
- B.C. Collings* and A.J. Silversmith, "Photon Avalanche in LaF3:Tm3+",
J Lumin. 62, 271 (1994).
- L. Zhang, P.D. Townsend, P.J. Chandler and A.J. Silversmith, "Upconversion
in ion implanted Er:YAG waveguides", Electronics Letters 30, 1063 (1994).
- A.J. Silversmith, W. Lenth, K.W. Blazey, and R.M. Macfarlane, "Photon Gated
Spectral Holeburning in SrTiO3:Cr3+", J. Lumin. 59,
269 (1994).
- A.J. Silversmith, "Upconversion Excitation of Green Fluorescence in Er:YAG",
J. Lumin. 60/61, 636 (1994).
- A.D. Novo-Gradac, S.M. Jacobsen, W.M. Dennis, W.M. Yen, and A.J. Silversmith,
"Infrared to Violet Upconversion in YLiF4:Nd", J. Lumin. 60/61, 695 (1994).
- A. J. Silversmith and R.M. Macfarlane, "Spectral-hole-burning study of the
hyperfine interaction in axial Eu3+ centers in CaF2, SrF2, and BaF2", Phys.
Rev. B 45, 5811 (1992).
- R. M. Macfarlane, A. J. Silversmith, F. Tong, and W. Lenth, "CW Upconversion
Laser Action in Neodymium and Erbium Doped Solids", Proceedings of the Conference
on Laser Materials and Laser Science, Shanghai, World Scientific, Singapore,
24 (1989).
- R. M. Macfarlane, F. Tong, A. J. Silversmith, and W. Lenth, "Violet CW Neodymium
Upconversion Laser", Appl. Phys. Lett. 52, 1300 (1988).
- W. Lenth, A.J. Silversmith, and R.M. Macfarlane, "Green Infrared-Pumped
Erbium Upconversion Lasers", Advances in Laser Science III, Ed. A.C. Tam,
J.L. Gole, W.C. Swalley, American Institute of Physics, NY (1988).
- W. Lenth, J.-C. Baumert, G. C. Bjorkland, R. M. Macfarlane, W. P. Risk,
F. M. Schellenberg, and A. J. Silversmith, "Compact Blue and Green Lasers
Based on Nonlinear Optical Processes", SPIE Vol. 898 Miniature Optics and
Lasers, 61 (1988).
- A. J. Silversmith, W. Lenth, and R. M. Macfarlane, "Green Infrared-pumped
Erbium Upconversion Laser", Appl. Phys. Lett. 51, 1977 (1987).
- N. B. Manson and A. J. Silversmith, "Rf Holeburning Within Inhomogenously
Broadened Raman Heterodyne NMR Signals", J. Phys. C, 20, 1507 (1987).
- A. J. Silversmith, A.P. Radlinski and N. B. Manson, "Optical Study of Hyperfine
Coupling in the 7F0 and 5D0 States
of Two Eu3+ Centers in CaF2 and CdF2", Phys.
Rev. B 34, 7554 (1986).
- A. J. Silversmith and N. B. Manson, "Determination of the 153Eu
- 151Eu Quadrupole Moment Ratio By Excited-State Optically Detected
Nuclear Magnetic Resonance", Phys. Rev. B 34, 4854 (1986).
- A. P. Radlinski and A. J. Silversmith, "Quadrupole Coupling and Crystal-Field
Shielding in CaF2:Eu3+:02- Under Hydrostatic
Pressure", Phys. Rev. B 34, 86 (1986).
- A. J. Silversmith, A. P. Radlinski and N. B. Manson, "Holeburning and ODNMR
Study of a Eu3+ Site in CaF2", J. de Phys. 46, C7-531
(1985).
- A. J. Silversmith and A. P. Radlinski, "Zeeman Spectroscopy of the G1 Center
in CaF2:Eu3+", J. Phys. C, 18, 4385 (1985).
- A. J. Silversmith and N. B. Manson, "Holeburning and Optically Detected
Nuclear Magnetic Resonance in CaSO4:Eu3+", J. Lumin
31/32, 848 (1984).
- A. J. Silversmith and N.B. Manson, "Optical Holeburning in KEu(WO4)2",
J. Phys. C 17, L97 (1984).
- T. J. Glynn, I. Laulicht, Liren Lou, A. J. Silversmith and W. M. Yen, "Trapping
of Optical Excitation by Two Types of Acceptor in La0.72Pr0.25Nd0.03F3",
Phys. Rev. B29, 4852 (1984).
- A.J. Silversmith, Liren Lou, And W.M. Yen, "Inhomogeneous Broadening in
the La1-xPrxF3 System", Phys. Rev. B26, 2656
(1982).
- W.H. Fuchsman and A.J. Silversmith, "General Method for Overcoming Photoacoustic
Saturation in Highly Colored Organic and Inorganic Solids", Anal. Chem.51,
589 (1979).
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Last modified 7/7/2005.
For questions or comments contact
Brian Collett
Physics Department
bcollett@hamilton.edu